19 September 2014
Last updated at 11:23 ET
The national split of the vote was 55% for "Yes" to 45% for "No".
Mr Salmond said: "For me as leader my time is nearly over but for Scotland the campaign continues and the dream shall never die."
Speaking from Bute House in Edinburgh, the first minister's official residence, he told journalists: "I am immensely proud of the campaign that Yes Scotland fought and particularly of the 1.6m voters who rallied to that cause."
Mr Salmond also said there were a "number of eminently qualified and very suitable candidates for leader", although the current deputy first minister Nicola Sturgeon, also deputy SNP leader, would be seen as a clear frontrunner.
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by Emily Straton and Biodun Iginla, BBC News
Alex Salmond is to step down as first minister of Scotland after voters decisively rejected independence.
He will also resign as leader of the Scottish National Party
(SNP) after the "No" side won Thursday's referendum by 2,001,926 to
1,617,989 for "Yes".The national split of the vote was 55% for "Yes" to 45% for "No".
Mr Salmond said: "For me as leader my time is nearly over but for Scotland the campaign continues and the dream shall never die."
Speaking from Bute House in Edinburgh, the first minister's official residence, he told journalists: "I am immensely proud of the campaign that Yes Scotland fought and particularly of the 1.6m voters who rallied to that cause."
Mr Salmond also said there were a "number of eminently qualified and very suitable candidates for leader", although the current deputy first minister Nicola Sturgeon, also deputy SNP leader, would be seen as a clear frontrunner.
This breaking news story is being updated and more details will be published shortly. Please refresh the page for the fullest version.
If you want to receive Breaking News alerts via email, or on a smartphone or tablet via the BBC News App then details on how to do so are available on this help page. You can also follow @BBCBreaking on Twitter to get the latest alerts.
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